Energy & Power

Nier Mass Spectrograph

Description

Background on Nier Mass Spectrograph; object id no. 1990.0446.01; catalog no. N-09567

This object consists of the following three components: ion source with oven and acceleration electrode; semicircular glass vacuum chamber; ion collector with two plates. The original device included an electromagnet, which is not part of this accession.

In 1939, as political tensions in Europe increased, American physicists learned of an astonishing discovery: the nucleus of the uranium atom can be split, causing the release of an immense amount of energy. Given the prospects of war, the discovery was just as worrying as it was intellectually exciting. Could the Germans use it to develop an atomic bomb?

The Americans realized that they had to determine whether a bomb was physically possible. Uranium consists mostly of the isotope U-238, with less than 1% of U-235. Theoreticians predicted that it was the nuclei of the rare U-235 isotope that undergo fission, the U-238 being inactive. To test this prediction, it was necessary to separate the two isotopes, but it would be difficult to do this since they are chemically identical.

Alfred Nier, a young physicist at the University of Minnesota, was one of the few people in the world with the expertise to carry out the separation. He used a physical technique that took advantage of the small difference in mass of the two isotopes. To separate and collect small quantities of them, he employed a mass spectrometer technique that he first developed starting in about 1937 for measurement of relative abundance of isotopes throughout the periodic table. (The basic principles of the mass spectrometer are described below.)

As a measure of the great importance of his work, in October 1939, Nier received a letter from eminent physicist Enrico Fermi, then at Columbia University, expressing great interest in whether, and how, the separation was progressing. Motivated by such urging, by late February 1940, Nier was able to produce two tiny samples of separated U-235 and U-238, which he provided to his collaborators at Columbia University, a team headed by John R. Dunning of Columbia. The Dunning team was using the cyclotron at the University in numerous studies to follow up on the news from Europe the year before on the fission of the uranium atom. In March 1940, with the samples provided by Nier, the team used neutrons produced by a proton beam from the cyclotron to show that it was the comparatively rare uranium-235 isotope that was the most readily fissile component, and not the abundant uranium-238.

The fission prediction was verified. The Nier-Dunning group remarked, "These experiments emphasize the importance of uranium isotope separation on a larger scale for the investigation of chain reaction possibilities in uranium" (reference: A.O. Nier et. al., Phys. Rev. 57, 546 (1940)). This proof that U-235 was the fissile uranium isotope opened the way to the intense U.S. efforts under the Manhattan Project to develop an atomic bomb. (For details, see Nier’s reminiscences of mass spectrometry and The Manhattan Project at: http://pubs.acs.org/doi/pdf/10.1021/ed066p385).

The Dunning cyclotron is also in the Modern Physics Collection (object id no. 1978.1074.01; catalog no. N-09130), and it will be presented on the SI collections website in 2015. (Search for “Dunning Cyclotron” at http://collections.si.edu/search/)

The Nier mass spectrometer used to collect samples of U-235 and U-238 (object id no. 1990.0446.01)

Nier designed an apparatus based on the principle of the mass spectrometer, an instrument that he had been using to measure isotopic abundance ratios throughout the entire periodic table. As in most mass spectrometers of the time, his apparatus produced positive ions by the controlled bombardment of a gas (UBr˅4, generated in a tiny oven) by an electron beam. The ions were drawn from the ionizing region and moved into an analyzer, which used an electromagnet for the separation of the various masses. Usually, the ion currents of the separated masses were measured by means of an electrometer tube amplifier, but in this case the ions simply accumulated on two small metal plates set at the appropriate positions. Nier’s mass spectrometer required that the ions move in a semicircular path in a uniform magnetic field. The mass analyzer tube was accordingly mounted between the poles of an electromagnet that weighed two tons, and required a 5 kW generator with a stabilized output voltage to power it. (The magnet and generator were not collected by the Smithsonian.) The ion source oven, 180-degree analyzer tube, and isotope collection plates are seen in the photos of the Nier apparatus (see accompanying media file images for this object).

Basic principles of the mass spectrometer

When a charged particle, such as an ion, moves in a plane perpendicular to a magnetic field, it follows a circular path. The radius of the particle’s path is proportional to the product of its mass and velocity, and is inversely proportional to the product of its electrical charge and the magnetic field strength. A mass spectrometer consists of three components: an ion source, a mass analyzer, and a detector. The ion source converts a portion of the sample into ions. There is a wide variety of ionization techniques, depending on the phase (solid, liquid, gas) of the sample and the efficiency of various ionization mechanisms for the unknown species. An extraction system removes ions from the sample and gives them a selected velocity. They then pass through the magnetic field (created by an electromagnet) of the mass analyzer. For a given magnetic field strength, the differences in mass-to-charge ratio of the ions result in corresponding differences in the curvature of their circular paths through the mass analyzer. This results in a spatial sorting of the ions exiting the analyzer. The detector records either the charge induced or the current produced when an ion passes by or hits a surface, thus providing data for calculating the abundance and mass of each isotope present in the sample. For a full description with a schematic diagram of a typical mass spectrometer, go to: http://www.chemguide.co.uk/analysis/masspec/howitworks.html

The Nier sector magnet mass spectrometer (not in Smithsonian Modern Physics Collection)

In 1940, during the time that Nier separated the uranium isotopes, he developed a mass spectrometer for routine isotope and gas analysis. An instrument was needed that did not use a 2-ton magnet, or required a 5 kW voltage-stabilized generator for providing the current in the magnet coils. Nier therefore developed the sector magnet spectrometer, in which a 60-degree sector magnet took the place of the much larger one needed to give a 180-degree deflection. The result was that a magnet weighing a few hundred pounds, and powered by several automobile storage batteries, took the place of the significantly larger and heavier magnet which required a multi-kW generator. Quoting Nier, “The analyzer makes use of the well-known theorem that if ions are sent into a homogeneous magnetic field between two V-shaped poles there is a focusing action, provided the source, apex of the V, and the collector lie along a straight line” (reference: A.O. Nier, Rev. Sci. Instr., 11, 212, (1940)). This design was to become the prototype for all subsequent magnetic deflection instruments, including hundreds used in the Manhattan Project.

Location

Currently not on view

Date made

ca 1940-02

associated person

Nier, Alfred O.

maker

Nier, Alfred O.

ID Number

1990.0446.01

accession number

1990.0446

catalog number

1990.0446.01

Data Source

National Museum of American History

Survey boat GRAND

Description

Grand is one of four boats used to survey the "ruggedest" 300 miles of the Colorado River's Grand Canyon during the 1923 expedition by the U.S. Geological Survey. Led by Col. Claude Birdseye, the expedition's primary purpose was to survey potential dam sites for the development of hydroelectric power. Indeed, the survey party mapped twenty-one new sites.

Grand is eighteen feet long, with a beam of four feet, eleven inches. Heavily built of oak, spruce, and cedar, the boat weighs about 900 pounds. Grand is one of three boats ordered in 1921 by the survey's sponsors, the Edison Electric Company, and built at the Fellows and Stewart Shipbuilding Works in San Pedro. The vessels were patterned after those designed by the Kolb brothers, who had based their boats on vessels used by trappers in the upper Colorado River canyons.

Location

Currently not on view

date made

1921

associated date

1923

associated institution

US Geological Survey

maker

Fellows and Stewart Shipbuilding Works

ID Number

TR.034381

catalog number

034381

34381

accession number

71541

Data Source

National Museum of American History

Multiwire proportional chamber from J-particle experiment of S. Ting at Brookhaven

Description

This object consists of a rectangular frame (steel, copper) holding signal wires (gold plated wires) separated by planes of high voltage wires (Cu-Be wire). Three planes of signal wires oriented at 60 degree increments; at +80, +20 and at -40. In operation, the entire chamber was filled with gas: 80% argon to provide an ionization medium for creating a detectable electrical signal; and 20% methylal, both as a spark extinguishing and as a cleaning agent (to prevent ageing of the wires due to carbon deposits). This chamber is one of four from left arm of the spectrometer setup at the Brookhaven Alternating Gradient Synchrotron (AGS), which measured electrons and positrons resulting from decay of a hypothesized massive "J" particle.

Basic Principles and History

A multiwire proportional chamber (MWPC) is constructed with alternating planes of high voltage wires (cathode) and sense wires (anode), which are at ground. All the wires are placed in a special gas environment. Spacing between planes is usually on the order of millimeters and voltage differences are typically in the kilovolt range. When a charged particle passes through the gas in the chamber, it will ionize gas molecules. The freed electrons are accelerated towards the sense wire (anode) by the electric field, ionizing more of the gas. In this way a cascade of charge develops and is deposited on the sense wires. The smaller the diameter of the sense wires, the higher the field gradient near the wire becomes. This in turn causes a larger cascade, increasing the efficiency of the chamber.

Georges Charpak built the first MWPC in 1968. Unlike earlier particle detectors, such as the bubble chamber and the first generation of spark chambers, which can record the tracks left by particles at the rate of only one or two per second, the multiwire chamber records up to one million tracks per second and sends the data directly to a computer for analysis. In 1992 Charpak received the Nobel Prize for Physics in acknowledgment of his invention of the MWPC, an electronic particle detector that revolutionized high-energy physics experiments and has had applications in medical physics.

The MWPC in the J-particle experiment of S.C.C. Ting at Brookhaven

The 1976 Nobel Prize in physics was shared by a Massachusetts Institute of Technology physicist who used Brookhaven's Alternating Gradient Synchrotron (AGS) to discover a new particle and confirm the existence of the charmed quark. Samuel C.C. Ting was credited for finding what he called the "J" particle, the same particle as the "psi" found at nearly the same time at the Stanford Linear Accelerator Center by a group led by Burton Richter. The particle is now known as the J/psi.

Ting's experiment took advantage of the AGS's high-intensity, 30 GeV proton beams, which bombarded a stationary beryllium target to produce showers of particles. The decay modes of these particles were identified using a two-arm spectrometer detection system. J particles decay into various combinations of lighter particles; one of these combinations is an electron and a positron. A small fraction of these enter the detection system, one particle in each arm of the spectrometer. Then dipole magnets deflect them out of the plane of the intense beam and measure their momentum; Cerenkov counters measure their velocity; multi-wire proportional chambers their position; scintillator hodoscopes their moment of passage; lead-glass and lead-lucite shower counters their total energy.

In each spectrometer arm there are 4 MWPCs (Ao, A, B, C) with 2 mm wire spacing and a total of 4,000 wires on each arm. There are eleven planes of proportional wires (2 in Ao, 3 each in A, B, & C), and in A, B, & C the planes are rotated 20 degrees with respect to each other to reduce multitrack ambiguities. To ensure the chambers have 100% uniform efficiency at low voltage and a long live time in the highly radioactive environment, a special argon-methylal gas mixture at 2 deg. C was used.

The identification of the J-particle and its significance

A strong peak in electron and positron production at an energy of 3.1 billion electron volts (GeV) led Ting to suspect the presence of a new particle, the same one found by Richter. Their discoveries not only won the Nobel Prize; they also helped confirm the existence of the charmed quark -- the J/psi is composed of a charmed quark bound to its antiquark.

The J/ψ (or J/psi) is a very special particle. Its discovery was announced in 1974 independently by two groups: one lead by Samuel Ting at Brookhaven National Laboratory (BNL) in New York and the second lead by Burton Richter at Stanford Linear Accelerator Center (SLAC) in California. J/ψ is special because it established the quark model as a credible description of nature. Having been invented by Gell-Man and Zweig as a bookkeeping tool, it was not until Glashow, Iliopoulos and Maiani (GIM) that the concept of quarks as real particles was taken seriously. GIM predicted that if quarks were real, then they should come in pairs, like the up and down quarks. Candidates for the up, down, and strange were identified, but there was no partner for the strange quark. J/ψ was the key.

Like the proton or an atom, the J/ψ is a composite particle. This means that J/ψ is made of smaller, more elementary particles. Specifically, it is a bound state of one charm quark and one anti-charm quark. Since it is made of quarks, it is a “hadron“. But since it is made of exactly one quark and one antiquark, it is specifically a “meson.”

For further details, see

http://hitoshi.berkeley.edu/129A/Cahn-Goldhaber/chapter9.pdf

http://www.nobelprize.org/nobel_prizes/physics/laureates/1976/ting-lecture.pdf

Location

Currently not on view

Date made

1972-1973

designer

Becker, Ulrich

ID Number

1989.0050.01.1

accession number

1989.0050

catalog number

1989.0050.01.1

Data Source

National Museum of American History

Preampliier for multiwire proportional chamber from J-particle experiment of S. Ting at Brookhaven

Description

One signal amplifier on rectangular plastic circuit board. Apparently one of these preamplifiers would have been plugged into one corresponding socket of Mulitwire Proportional Chamber 1989.0050.01.1. A sticker accompanying this object reads "8 wire signals [from associated socket on chamber] get amplified .0002V to .8V" (to output to the computer). Similarly for all sockets of all four chambers in each of the two arms of the spectrometer setup at the Brookhaven Alternating Gradient Synchrotron, which was used to measure electrons and positrons resulting from decay of a hypothesized massive "J" particle.

Rectangular green plastic circuit board, with electronic components soldered on upper surface. As viewed from front of board: at left end of bottom edge are 12 contact strips, only 8 of which are connected to the circuits. Near the right end of the bottom edge are 10 such contact strips. Protruding from right edge are 10 pairs of short wires, which are inserted into a green plastic connector fitting, which has 9 contact sockets on the other side.

For background on the multiwire proportional chamber from J-particle experiment of S. Ting at Brookhaven see description for object ID no. 1989.0050.01.1

Location

Currently not on view

date made

1972-1973

designer

Becker, Ulrich

ID Number

1989.0050.01.2

accession number

1989.0050

catalog number

1989.0050.01.2

Data Source

National Museum of American History

Phrenological bust of Thomas Alva Edison

Description

In 1878 Thomas Edison had achieved international renown due to his invention of a machine that could talk: the phonograph. His inventive activities in the field of telegraphy were well known in that important industry. Although his most prolific days as an inventor lay ahead, people understood that "the Wizard of Menlo Park" was someone to be taken seriously.

This bust of Edison was made in 1878 for the Phrenological Institute of New York. Phrenology (today dismissed as false science) involved the study of the shape and size of people's heads. Phrenologists believed that one could measure and rank factors like intellegence, honesty and creativity through a close study of the external features of the head. An accurate record of Edison's head would preserve a record of someone perceived as quite creative and intellegent, allowing comparisions to be made to a known standard.

The bust was made by J. Beer, Jr.

Date made

1878

1878

associated person

Edison, Thomas Alva

maker

S. R. Wells & Co.

ID Number

EM.310582

catalog number

310582

accession number

123470

Data Source

National Museum of American History

Standard Tungsten Lamp

Description

Irving Langmuir received a Ph.D. in physical chemistry in 1906 from the University of Göttingen. He studied under Walther Nernst, who had invented a new type of incandescent lamp only a few years before. In 1909 Langmuir accepted a position at the General Electric Research Laboratory in Schenectady, New York. Ironically, he soon invented a lamp that made Nernst's lamp (and others) obsolete.

Langmuir experimented with the bendable tungsten wire developed by his colleague William Coolidge. He wanted to find a way to keep tungsten lamps from "blackening" or growing dim as the inside of the bulb became coated with tungsten evaporated from the filament. Though he did not solve this problem, he did create a coiled-tungsten filament mounted in a gas-filled lamp—a design still used today.

Up to that time all the air and other gasses were removed from lamps so the filaments could operate in a vacuum. Langmuir found that by putting nitrogen into a lamp, he could slow the evaporation of tungsten from the filament. He then found that thin filaments radiated heat faster than thick filaments, but the same thin filament–wound into a coil–radiated heat as if it were a solid rod the diameter of the coil. By 1913 Langmuir had gas–filled lamps that gave 12 to 20 lumens per watt (lpw), while Coolidge's vacuum lamps gave about 10 lpw.

During the 1910s GE began phasing-in Langmuir's third generation tungsten lamps, calling them "Mazda C" lamps. Although today's lamps are different in detail (for example, argon is used rather than nitrogen), the basic concept is still the same. The lamp seen here was sent to the National Bureau of Standards in the mid 1920s for use as a standard lamp.

Lamp characteristics: Brass medium-screw base with skirt and glass insulator. Two tungsten filaments (both are C9 configuration, mounted in parallel) with 6 support hooks and a support attaching each lead to the stem. The stem assembly includes welded connectors, angled-dumet leads, and a mica heat-shield attached to the leads above the press. The shield clips are welded to the press. Lamp is filled with nitrogen gas. Tipless, G-shaped envelope with neck.

Date made

ca 1925

date made

ca. 1925

ID Number

1992.0342.23

accession number

1992.0342

catalog number

1992.0342.23

Data Source

National Museum of American History

Non-ductile Tungsten Lamp

Description

Thomas Edison and others considered element number 6, carbon, ideal for lamp filaments in part because it has the highest melting point of any element. Element number 74, tungsten, has the next highest melting point but it then existed only as a powder. Attempts to make it into a workable form failed until early in the 1900s when a burst of invention occurred in Europe. A pressing technique called "sintering" (squeezing a material into a dense mass) was adopted by several inventors.

The most commercially successful design proved to be that of Dr. Alexander Just and Franz Hanaman of Austria. Their work on sintering tungsten was based on a prior sintering process developed by Carl Auer von Welsbach for his filament made of osmium. Just and Hanaman made a tungsten and organic paste, squirted it through a die, baked out the organic material, then sintered the tungsten in a mix of gasses. The resulting filament gave about 8 lumens per watt and lasted 800 hours.

Another Austrian, Dr. Hans Kutzel, used an electric arc to make a tungsten and water paste. He then pressed, baked, and sintered the tungsten in a manner similar to Just and Hanaman's procedure. Yet another pair of Austrians, Fritz Blau and Hermann Remane, adapted the osmium lamp process (they worked for Welsbach) by making a filament from an osmium and tungsten mix. They soon changed their "Osram" lamp filament to tungsten only. (The German word for tungsten is wolfram.)

All three filaments were brittle and collectively known as "non-ductile" filaments. Individual filaments could not be made long enough to give the proper electrical resistance, so lamps needed several filaments connected end-to-end. U.S. companies quickly licensed rights to all of the non-ductile patents. This particular lamp was made under license by General Electric and sent to the National Bureau of Standards for use as a standard lamp.

Lamp characteristics: Medium-screw base with glass insulator. Five single-arch tungsten filaments (in series) with 5 upper and 8 lower support hooks. The stem assembly features soldered connectors, Siemens-type press seal, and a cotton insulator. Tipped, straight-sided envelope with taper at neck.

Date made

ca 1908

date made

ca. 1908

maker

General Electric

ID Number

1992.0342.16

catalog number

1992.0342.16

accession number

1992.0342

Data Source

National Museum of American History

Edison ammeter

Date made

c1882

ca 1882

associated person

Edison, Thomas Alva

maker

Bergmann & Co.

ID Number

EM.331146

accession number

294351

catalog number

331146

collector/donor number

20-03

Data Source

National Museum of American History